Editorial

Dear Readers,

After the successful completion of the acquisition of Rhodia last year, Solvay has received a new look. With a fresh logo, Solvay shows the connection between tradition and pioneer of a sustainable chemistry. In the course of the redesign, Solvay Special Chemicals also revised the NOCOLOK brand. The NOCOLOK lettering and four icons from the aluminium brazing sector form the new logo. And thus the NOCOLOK News has also received a facelift. Information all around aluminium brazing is offered in a clear and well-structured fashion. Whether on a computer, a laptop, a tablet or smartphone, the NOCOLOK News always looks good.

We hope you enjoy reading – interesting topics are waiting for you. From 2014 we will be producing NOCOLOK in our new plant in Quzhou, near Hangzhou in China and in our Tech Tips we will answer the FAQs about the brazing of aluminium heat exchangers. And if you would like to meet us personally – the NOCOLOK team can be found in Essen, Germany at the “Schweißen & Schneiden”, in Sao Paulo, Brazil at the Brazil Welding and we will be training participants at the EABS seminar in Hannover.

Your Werner Schmitt



Global Business Unit Special Chemicals
Global Sales & Marketing Manager
NOCOLOK®/Inorganics

Solvay to invest in production facility for NOCOLOK® in China

Lansol Fluorchemicals, a joint venture between Solvay and Sinochem Lantian, a Chinese chemical company, is building a production facility for NOCOLOK, a brazing flux, in Quzhou (Zhejiang province). The Solvay group will be investing €5 million in the project. Production is to begin by the spring of 2014, to produce around 3,000 tonnes p.a.

“The new facility is an example of the Solvay group’s strategy to invest in growing markets and to expand production and development sites close to our markets and customers“, says Horst Kröger, Manager Business Development and Strategy of Solvay’s Global Business Unit (GBU) Special Chemicals.

With its fluorine specialty NOCOLOK Solvay is a global market leader for aluminium brazing flux. In the automotive industry the brazing flux is the standard for the production of heat exchangers such as coolers and air conditioning systems. With the new production facility Solvay aims to serve the fast-growing automotive market in Asia, and specifically in China.

The Solvay group has had a cooperation with the Sinochem Lantian Group since 2006. “Our good experiences with our Chinese partner have encouraged us to expand the cooperation further“, Kröger explains. At the Quzhou site near Hangzhou, in Zhejiang province in East China, Lansol with its 97 employees operates a facility for the production of hydrogen fluoride and for highly pure hydrofluoric acid (HF), which Lansol mainly sells to the two partners in the joint-venture in China (Sinochem Lantian) and in Korea (Solvay) for their own processing demands. In addition, Lansol also sells HF to the domestic solar panel industry and to export customers in Korea.

The new NOCOLOK plant is to start producing by July 2014. The groundbreaking ceremony was held in July 2013. The new facility will offer approx. 25 new jobs. “We will begin by producing around 3,000 tonnes p.a. of NOCOLOK, but we can adapt our production capacity very quickly if demand increases“, says Kröger.

NOCOLOK® App goes BlackBerry

Solvay Special Chemicals bundles all the information on aluminium brazing in a smartphone App. The NOCOLOK Flux-App puts all the information you need for your day-to-day business right where you need it – at your fingertips.

Now the NOCOLOK App is available for BlackBerry smartphones in the BlackBerry World. This is another logical move in Solvay Fluor’s strategy of providing a full service on all aspects of aluminium brazing for all users. After iOS and Android now the app is ready for BlackBerry in version 2.111. Your BlackBerry device needs min. the Operating System 7.1.0 or higher.

The App boasts a detailed product overview of all NOCOLOK fluxes and ancillary products, as well as their physical properties and GHS classifications. From brazing, welding, soldering, powder coating to perfect corrosion protection: the App lists the packaging units, together with their weights, dimensions and a picture to simplify the selection of the required product.

But the real highlights of the application are the calculators – which really help your day-to-day routines: the “Flux Slurry Calculator” calculates the amount of NOCOLOK Flux needed dependent on the number of litres required and the concentration of the slurry. Two additional calculators for increasing or decreasing the slurry concentration are available too. The “Flux Load Calculator” calculates the surface of a heat exchanger and the amount of flux required for the brazing process. Additionally detailed answers on fundamental aspects and special features of aluminium brazing with NOCOLOK are provided at a touch by the “NOCOLOK Encyclopaedia”.

The App is dedicated for users handling aluminium brazing, flux, solder, brazing alloy and CAB.

Please scan the QR-Code with QR Code Scanner.

Upcoming Events

Aluminium Brazing Live on the Stand

Solvay Fluor is taking part at the Schweißen & Schneiden 2013 and presents two main topics at the show at hall 11, stand A123:

NOCOLOK Aluminium Brazing Fluxes

Solvay Fluor is the leading pioneer for aluminium brazing – and has been for years. With our revolutionary NOCOLOK Flux we are the global market leader and trendsetter – our customers know: “NOCOLOK products are more than just a flux!” A wide net of specialists stretches across the globe locally supporting our customers. And, our research technologists continue to develop the best flux for your application. Connected global thinking and local support. NOCOLOK Flux without frontiers. Solvay Fluor will present the glass demonstration furnace for aluminum brazing with NOCOLOK Flux live on the stand.

Inorganic Fluorides

Cryolite, Potassiumfluoroaluminate, Potassiumfluoroborate and other inorganic Fluorides are used as active fillers in abrasive materials to improve its performance. Solvay Fluor is one of the leading producers.

www.schweissen-schneiden.com

Watch the preview of the show on DVS-TV (in German language).

Only a few places left

Seminar: The Theory and Practice of the Flame and Furnace-Brazing of Aluminium

EABS and Solvay Fluor GmbH announce the twelfth annual presentation of their joint technical training seminar entitled:

Dates: 24th and 25th September 2013

Please download your Seminar Registration Form here

Purpose of the Seminar:

This technical training seminar will be presented in the English language at the Conference Centre and laboratories of SOLVAY GmbH, in Hannover, Germany. It will provide information concerning the manufacturing practices commonly used for brazing operations and, in particular, will address the three fundamental aspects of the industrial-scale brazing of aluminium.

These are:

  • The flame brazing of aluminium.
  • The Controlled Atmosphere Brazing (CAB) of aluminium heat exchangers with non-corrosive fluxes (NOCOLOK Flux).
  • The methodology of how to ensure that the brazing process selected is, indeed, the one that represents ‘best practice’.

Register today!

Brazil Welding Show 2013

The Brazil Welding Show will take place for the second time after the 2011 show in Sao Paulo. From 1st to 4th October 2013, the industry will meet in the Brazilian metropolis to showcase the latest welding and joining technologies to the growth market. Solvay Fluor is present in collaboration with Solvay do Brasil and the specialists from the NOCOLOK team will be presenting the flux for aluminium brazing to the trade visitors.

We look forward to seeing you on stand 47, Pavilion “red” at the Expo Center Norte!

www.brazil-welding-show.com

Anniversary at the NOCOLOK production in Wimpfen

At the end of June 2013 the time had finally come. The 20,000 NOCOLOK mixer was put into action at the Solvay plant in Wimpfen.

NOCOLOK has been produced there since March 1983 and the development of the production is as impressive as the increase in production output. In 1993 the 1,000, 2,000 and 5,000 and in 2005 the 10,000 mixer was applied.

A reason to celebrate! “My thanks to all the staff at the plant and to our customers who have been using our products for years,” says Ulf Unverricht, NOCOLOK Production Manager. “Bad Wimpfen is the location for high quality NOCOLOK specialities. The plant has the experience and that know-how is essential when building new locations such as Quzhou in China.”

NOCOLOK Survey

First of all we would like to sincerely thank all the readers who have already participated in our NOCOLOK satisfaction survey.

The iPad Mini, which we raffled among the participants in the last quarter, has found a lucky winner. And again in this quarter, among all participants taking part in the NOCOLOK survey between the July 1st and September 30th, we will be raffling a super prize: a tablet Asus Google Nexus 7 32GB Wi-Fi, model year 2013. And, you have a second chance to win early next year: among all 2013 participants we will be raffling a PlayStation 4.

Simply click, select your language, answer questions and you're there. We look forward to your opinions!

Click here for the survey

Picture by Denis

Technical Information

FAQ about All-Aluminium Brazed Heat Exchangers
in HVAC&R Industry – Part1

Summary

The article was written on the basis of frequently asked questions from companies which either wanted to start a new all-aluminium brazing production of heat exchangers or wanted to convert from copper and aluminium mechanical assembly design to all-aluminium brazed parts. The questions were grouped into three main categories: Equipment (emphasis on assembling process), Process (emphasis on different fluxes and fluxing methods) and Corrosion.

Specific production challenges are also presented, which are important not only to newcomers of all-aluminium brazed heat exchangers, but to established companies as well. These include typical brazing problems such as managing leaks and the basics of brazing copper to aluminium. These topics are discussed by their relevance to the brazing parameters and their role in successful brazing.

1. Introduction

Brazing Furnace

Increasing environmental concern has identified the air conditioning and refrigeration industry as one of the contributors to the greenhouse effect and ozone depletion.

Accordingly to [1] 15% of all electricity consumption in the developed world is used by the air conditioning and refrigerator industry. Increasing the efficiency of these heat transfer systems has the positive impact of decreasing electricity consumption and therefore the overall emission of CO2. The advantages of all aluminium brazed condensers in an air conditioning system are well described in [2]. For example one such case study [3] allowed for saving about 2700 USD during 6 months. The above advantages are currently well recognized by both the air conditioning manufacturers and their end users. It is our observation that the majority of the companies in the HVAC industry which have started or are about to start production of aluminium brazed heat exchangers have only limited experience with aluminium brazing; therefore providing them with maximum possible technical assistance from the supplier side is of high importance.

This article was written on the basis of our contacts with such companies having an aim to offer some assistance to all newcomers and companies facing some troubles with their new type of production.

2. Equipment

In most cases, the first question from a company that wants to start a new aluminium brazing activity is: “What kind of furnace should I buy?”

It is a complex issue which mainly depends on size of the products, its diversity and overall planned production volume. The general principles for the choice of the brazing furnace are shown in Fig. 1. It should be pointed out that the furnace manufacturers will make a brazing furnace customized to particular requirements of a given client.

Assembling units

In many cases the companies which are starting production of all aluminium brazed heat exchangers have been producing copper brazed heat exchangers. Therefore the natural question is: ”Can I use the same equipment which is used for copper units?”

The straight forward answer is: No! Aluminium requires high precision for assembling (recommended gap size is 0.1 to 0.15mm), which is hardly ever achieved for brazing copper parts. Also one should remember that any copper contamination on aluminium can cause catastrophic brazing failures (holes).

The process of component assembly can be done on a simple manual stacker or on machines with varying degrees of automation through to fully automated units. The level of automation should be mainly determined by the planned production volume, but also other factors such as local labour costs should also be considered.

Basic requirements for a manual assembling unit:

  1. Cores must be assembled on a perfectly flat heavy steel plate
  2. After laying out the tubes and fins, the tubes must be pushed precisely into position determined by the slots in the headers.
  3. To secure the above requirement:
    1. movement of the pusher must be allowed only in one direction (no side or up movement),
    2. travel distance must be accurately controlled – e.g. by mechanical block on the pusher,
    3. it is useful to have a special distances between tubes to secure the right spacing for each header slot,
    4. the vertical alignment of the tubes must be secured either by steel plate or by hammering the tubes with a special pad.
  4. Threading the headers on the tubes should be done in one single action which does not allow for any side or vertical deflection of the headers.
  5. After threading the headers the fixtures should be assembled and the tube pusher released.

The process of the part assembly is invariably connected with fixtures; these are the steel elements which hold the parts together during brazing and then removed after brazing. The most frequently asked question is: ”What should be the design of the brazing frames/fixtures?”

Basically there are rigid and elastic designs which allow for some expansion when the core is heated. For larger cores elastic design is preferred. This type of fixture is reusable, also known as a permanent fixture and can go through the brazing cycle several hundred times. Apart from that we could use single usage fixtures, known as disposable fixtures and these include steel wire and steel bands. The multi-use fixtures must be made of stainless steel and in most cases the single use fixtures are usually made of ordinary low carbon steel.

When designing the length of the fixture (distance marked in red as Ls in fig. 2, one must remember thatthere is a difference in thermal expansion coefficient between aluminium and steel. To compensate for this, the following assumption is made: The length of the steel fixture at brazing temperature must be equal to the nominal width of the aluminium exchanger at brazing temperature. On this basis, an equation can be used describing the linear change of dimensions with temperature.

Ls(1 + αstΔt) = Lo(1 + αalΔt)

Where:
Ls – length of steel fixture,
αst – thermal expansion coefficient for the fixture material,
αal – thermal expansion coefficient for aluminium,
Δt – Increase of the part temperature during brazing,
Lo – Nominal width of the part.

As an example, for a part having width of 900 mm and nominal tube spacing of 8 mm, solving this equation and taking into account the fact that after assembly there must be some pressure exerted by the fixture on the part, the length of the fixture should be 907.5 mm and the fin height 8.08 mm. The longer steel fixture is compensated by the increased fin height. It also means that after assembly the part will have a slightly barrel-like shape (bowed out at the sides).

The question: ”What final checks are required for brazed parts?” is also connected to equipment purchases. All brazed parts must be checked for leak tightness. The most simple method is the so called “under water test”. In this case the part is pressurized with air and lowered into a water bath to look for bubbles. However some end users require more accurate and reliable methods. In the automotive industry it is common to check condensers for leaks with high pressure and extremely sensitive helium leak detection devices.

Each product should be accepted by the end user. In every case the scope of acceptance tests should be agreed to between the manufacturer and the end users. Typical tests include burst pressure, thermal cycling and of course standard ones for heat transfer efficiency and pressure drop. As a general rule it can be said that all aluminium parts should meet all the requirements applied to copper/brass parts.



References:

  1. Hans W. Swidersky, “Brazed Aluminium Heat Ex-changers for the Refrigeration and Air Conditioning Industry”, APT Aluminium News, 1-2009
  2. Bjørn Vestergaard, “Brazed Aluminium Heat Ex-changers – Ask for the inexpensive features”, Seminar “Aluminium Process-Technology for HVACR Industry” Vienna, March 21st-23rd, 2007
  3. Case Study – Harris County Sheriff’s Building, “Carrier Turn to the Experts” 2006 Carrier Corporation 05/06 04-811-10206