Process related causes

The service life of a heat exchanger may be shortened due to corrosion caused by process related events. Some examples are listed below:

Excessively high brazing temperature or too long time at temperature will lead to excessive Si diffusion in the core. Si diffuses along grain boundaries and this can increase the susceptibility to intergranular corrosion. By maintaining proper time-temperature cycles and thereby minimizing Si diffusion, intergranular attack can also be minimized.

Copper in contact with aluminum will cause a corrosion related failure very quickly. Copper is noble (cathodic) to aluminum and when these two metals are in contact in the presence of an electrolyte, the aluminum will be consumed rapidly. This may occur in a heat exchanger manufacturing facility where both Al and Cu heat exchangers are produced and there is cross-contamination of process routes. It only takes one small Cu chip to land on the surface of Al during some part of the manufacturing process to cause a short-term failure in the Al heat exchanger. If both Al and Cu heat exchangers are to manufactured under the same roof, it is recommended (and practiced) to physically separate the two production routes with a wall and take extensive steps to avoid cross-contamination.

Carbonaceous residues can be generated on the heat exchanger surfaces during the heat cycle from residual lubricants, excessive use of surfactants, binders in flux or braze pastes etc. Carbon plays very much the same role as Cu in that it is noble to Al. In a corrosive environment, carbon residues act as a cathode and Al as an anode, leading to the galvanic corrosion of Al. The best preventative measure is to ensure that the heat exchangers are thoroughly and properly cleaned and degreased prior to brazing. This includes monitoring the flux slurry bath for any signs of organic contamination (for instance oil slicks).

Coatings

Painting a heat exchanger offers some level of corrosion protection, but is primarily used for cosmetic purposes. Painting will enhance corrosion protection if it covers the entire heat exchanger uniformly and is free from defects. In fact, paint defects or stone chips will accelerate corrosion locally. Many Al producers believe it is better to leave the heat exchanger unpainted to prolong its service life.

Conversion coatings such as chromate or phosphate conversion coatings work differently than painted surfaces. Conversion coatings enhance the natural oxide film on Al, essentially making it thicker and more resistant to hydrolysis. These types of coatings are most often used with automotive evaporators.

2 replies
  1. plumbing
    plumbing says:

    Corrosion might due to the chemicals flowing on the pipe, or chemicals and bacteria mixed on the water. Corrosive part of the pipe must be replace or repair to avoid bigger problem.

    Reply
  2. Dr. Hans Swidersky
    Dr. Hans Swidersky says:

    After brazing of aluminium with NOCOLOK, the flux residue remains on the surfaces as a very thin adherent film with a thickness of a few microns – depending on the original flux load. It is generally accepted in the brazing industry that the presence of this flux residue has no significant effect on corrosion resistance at standard service conditons. In corrosion testing of flat panels or coupons coated with flux residue, there is no doubt that there is even a beneficial effect. With aluminium heat exchangers on the other hand, the general trend shows a longer corrosion life, but factors such as uniformity of flux residue coverage and variations in flux loadings sometimes influence the corrosion test data. There are several other factors – e.g.: aluminium alloy composition, exposure to corrosive chemicals, environmental exposure, and service conditions – that will affect corrosion performance.

    Reply

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